Easily Modified Directing Groups for the Palladium-Catalyzed C-H Functionalization

被引:16
|
作者
Wang, Yong [1 ]
Cheng, Guolin
Cui, Xiuling
机构
[1] Huaqiao Univ, Minist Educ, Engn Res Ctr Mol Med, Xiamen 361021, Peoples R China
关键词
C-H functionalization; palladium catalyzed; directing groups; regioselectivity; AEROBIC ALCOHOL OXIDATION; CROSS-COUPLING REACTIONS; ORTHO-ARYLATION; BOND ACTIVATION; ALPHA-ARYLATION; STEREOSELECTIVE-SYNTHESIS; ALIPHATIC PALLADATION; ORTHO-HALOGENATION; 2-PYME2SI GROUP; SIMPLE ARENES;
D O I
10.6023/cjoc201205026
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium-catalyzed C-H functionalization is one of the hot topics in the field of organic synthesis methodology. Directing groups play an important role in the regioselectivity of C-H activation. Herein, this review presents the recent progress on the removable and transformable directing groups for the palladium-catalyzed C-H bonds activation and their applications in the synthesis of complicate molecules. Moreover, the research trend of this area is also prospected.
引用
收藏
页码:2018 / 2039
页数:22
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