Molecular wave packet dynamics decelerated by solvent environment: A theoretical approach

被引:3
|
作者
Thallmair, S. [1 ,2 ]
Kowalewski, M. [1 ,3 ]
Fingerhut, B. P. [1 ,4 ]
Sailer, C. F. [2 ]
de Vivie-Riedle, R. [1 ]
机构
[1] LMU Munchen, Dept Chem, Butenandtstr 11, D-81377 Munich, Germany
[2] LMU Munchen, LS BioMol Opt, D-80538 Munich, Germany
[3] Uppsala Univ, Dept Informat Technol, S-75105 Uppsala, Sweden
[4] Univ Calif Irvine, Dept Chem, Irvine, CA 92717 USA
关键词
D O I
10.1051/epjconf/20134105043
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present a new dynamic continuum ansatz to describe the frictional force exerted on moving wave packets in a solvent cage. The solvent interferes on the femtosecond time scale, but decides the reaction outcome.
引用
收藏
页数:3
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