1-D and 2-D lanthanide coordination polymers constructed from 4-sulfobenzoate and 1,10-phenanthroline

被引：19
|
作者：
Li, Xia [1 ]
Li, Yan-Qiu [1 ]
Wu, Xiao-Shuo [1 ]
机构：
[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 07期
关键词：
lanthanide coordination polymers; 4-sulfobenzoic acid; hydrothermal synthesis; crystalstructure; luminescence;
D O I：
10.1016/j.inoche.2008.03.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two complexes {[Dy-2(4-SBA)(3)(phen)(2)(H2O)(4)]center dot 2H(2)O}(n) (1) and {[Eu-2(4-SBA)(3)(phen)(2)( H2O)(2)]}(n). (2) (4SBA = 4-sulfobenzoate, phen = 11,11 0-phenanthroline) were synthesized and their structures were determined by X-ray crystallography. The I has a 1-D chain structure by bidentate and tridentate 4-SBA ligands as linkages and 3-1) network was formed by strong hydrogen bonds. The 2 has a 2-D network structure by tridentate and tetradentate 4-SBA ligands as linkages. The luminescence properties and thermal stability of the two complexes were investigated. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：774 / 778
页数：5
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