Studies on spectroscopic and crystal structure of dichloro carbonyl dipyridine triphenylarsine ruthenium(II) complex

被引：0

作者：

Gowri, M. ^{[1
]}

Srinivasan, T. ^{[2
]}

Velmurugan, D. ^{[2
]}

机构：

[1] Avinashilingam Univ Women, Dept Chem, Coimbatore 641043, Tamil Nadu, India

[2] Univ Madras, CAS Crystallog & Biophys, Chennai 600025, Tamil Nadu, India

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 08期

关键词：

Ru(II) complex; triphenyl arsine; pyridine; chloride; carbonyl complex; crystal structure; HYDROGENATION; ISOMERIZATION; LIGANDS; ALDEHYDES; CATALYSTS; HYDRATION; ALCOHOLS; WATER;

D O I：

10.1134/S0022476615080223

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex [Ru(Cl)(2)(CO)(py)(2)(AsPh3)], was synthesized and characterized. The molecular structure and crystal structures are determined by X-ray crystallography. The dihedral angle between the two cis-pyridine rings is 73.3(2)A degrees, which shows that they are almost orthogonal to each other. The molecular structure is stabilized by inter-molecular and intra-molecular C-HaEuro broken vertical bar Cl interactions. The molecular structure is further stabilized by interactions between the aromatic rings.

引用

页码：1602 / 1605

页数：4

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