Citrate-assisted hydrothermal synthesis of vanadium dioxide textured films with metal-insulator transition and infrared thermochromic properties

被引：11

作者：

Ivanov, Alexey, V ^{[1
,2
]}

Makarevich, Olga N. ^{[3
]}

Boytsova, Olga, V ^{[2
]}

Tsymbarenko, Dmitry M. ^{[3
]}

Eliseev, Andrei A. ^{[1
]}

Amelichev, Vadim A. ^{[4
]}

Makarevich, Artem M. ^{[2
,4
]}

机构：

[1] Lomonosov Moscow State Univ, Dept Mat Sci, Moscow 119991, Russia

[2] RAS, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[3] Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[4] SuperOx, 20-2 Nauchnyi Proezd, Moscow 117246, Russia

来源：

CERAMICS INTERNATIONAL | 2020年 / 46卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

Vanadium dioxide; Films; Hydrothermal synthesis; Electrical properties; Optical properties; VO2; NANOSTRUCTURES; TRANSFORMATION; TEMPERATURE; CAMOUFLAGE; NANOSHEETS; CATHODE; ACID;

D O I：

10.1016/j.ceramint.2020.05.058

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The present study reports the fast synthesis of VO2 (M-1) oriented films on the r-Al2O3(012) substrates by the hydrothermal method using citric acid and vanadium (V) oxide as precursors with post deposition annealing in inert atmosphere. The effects of synthesis parameters (solution concentration and autoclave filling factor) on the films composition, morphology and electric properties are considered using XRD, Raman spectroscopy, AFM and SEM. The obtaining VO2(M-1)/r-Al2O3 films show a metal-insulator transition with resistivity change of similar to 3.5 orders of magnitude and excellent thermochromic properties in the long-wavelength IR region. This work demonstrates a promising technique to promote the commercial implementation of VO2 as material for design of infrared (IR) switch devices.

引用

页码：19919 / 19927

页数：9

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