A potential refinery process of light-light naphtha olefins conversion to valuable oxygenated products in aqueous media - Part 1: Biphasic hydroformylation

被引：10

作者：

Kokkinos, Nikolaos C. ^{[1
]}

Kazou, Evaggelia ^{[1
]}

Lazaridou, Anastasia ^{[1
]}

Papadopoulos, Christos E. ^{[1
]}

Psaroudakis, Nikolas ^{[2
]}

Mertis, Konstantinos ^{[2
]}

Nikolaou, Nikolaos ^{[1
]}

机构：

[1] Kavala Inst Technol, Fac Engn, Dept Petr & Nat Gas Technol, Ag Loukas 65404, Kavala, Greece

[2] Univ Athens, Fac Chem, Dept Inorgan Chem, GR-15771 Athens, Greece

来源：

FUEL | 2013年 / 104卷

关键词：

Naphtha; Refinery process; Hydroformylation; Rhodium/TPPTS; Aqueous biphasic catalysis; FLAME IONIZATION DETECTOR; HOMOGENEOUS CATALYSIS; WATER; HYDROGENATION; COMPLEXES; ALDEHYDES; PRESSURE; ALKENES; SYSTEMS; COBALT;

D O I：

10.1016/j.fuel.2012.08.040

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The serious drawbacks from the use of oxygenates (MTBE, ETBE, TAME) from the refineries, in order to meet the current specifications of gasolines, could be overcome by using aqueous biphasic hydroformylation of alkenes from the light-light cracked naphtha (LLCN). This in situ and environmentally friendly catalytic process increases the concentration of molecular oxygen on the fuel by producing favorable oxygenated compounds (aldehydes or even alcohols), it improves the combustion properties and the storage stability of the fuel and it also increases the FON and the RON of the ultimate fuel. For the first time, hydroformylation of olefins present in a refinery (real) light light cracked naphtha was carried out in aqueous media. The influence of the reaction pressure (25-100 bar), temperature (30-130 degrees C) and reaction time (3-24 h), as well as the effect of the TPPTS/Rh (2-6) and olefins/Rh (125-1500) molar ratios were examined. The highest conversion of 95.4% of the olefins was observed at 70 degrees C, 100 bar, at a short reaction time (6 h). (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：275 / 283

页数：9