MIL-100(Fe)-catalyzed efficient conversion of hexoses to lactic acid

被引：88
|
作者：
Huang, Shan [1 ]
Yang, Kai-Li [1 ]
Liu, Xiao-Fang [1 ]
Pan, Hu [1 ]
Zhang, Heng [1 ]
Yang, Song [1 ]
机构：
[1] Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Key Lab Green Pesticide & Agr Bioengn,Minist Educ, Ctr Res & Dev Fine Chem,State Local Joint Lab Com, Guiyang 550025, Peoples R China
来源：
RSC ADVANCES | 2017年 / 7卷 / 10期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; SOLID LEWIS-ACIDS; CATALYTIC TRANSFORMATION; HETEROGENEOUS CATALYSIS; SUGAR CONVERSION; METHYL LACTATE; LEVULINIC ACID; C-C; SITES; FE;
D O I：
10.1039/c6ra26469g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
MIL-100(Fe) was used for the first time in the catalytic transformation of hexose sugars into lactic acid (LA). The as-synthesized MIL-100(Fe) was systematically characterized, and its superior morphological and textural properties were demonstrated to contribute greatly to the pronounced catalytic performance in fructose-to-LA conversion (up to 32% yield), as compared with other catalysts like Cu-BTC and MIL-100(Cr). The effects of reaction conditions including temperature, reaction time, and substrate loading were explored. In addition, MIL-100(Fe) could be easily reused for 4 cycles with no evident decrease in catalytic activity.
引用
收藏
页码：5621 / 5627
页数：7
相关论文
共 50 条
  • [1] An efficient Ag/MIL-100(Fe) catalyst for photothermal conversion of CO2 at ambient temperature
    Jing, Peng
    Wu, Boyuan
    Han, Zongsu
    Shi, Wei
    Cheng, Peng
    CHINESE CHEMICAL LETTERS, 2021, 32 (11) : 3505 - 3508
  • [2] An efficient Ag/MIL-100(Fe) catalyst for photothermal conversion of CO2 at ambient temperature
    Peng Jing
    Boyuan Wu
    Zongsu Han
    Wei Shi
    Peng Cheng
    ChineseChemicalLetters, 2021, 32 (11) : 3505 - 3508
  • [3] MIL-100(Fe) Catalyzed Self-Condensation of n-Valeraldehyde
    Wang, Di
    Li, Bu-Wei
    An, Hua-Liang
    Zhao, Xin-Qiang
    Wang, Yan-Ji
    Jingxi Huagong/Fine Chemicals, 2019, 36 (01): : 94 - 100
  • [4] Exploring the electrosynthesis of MIL-100(Fe) derivatives
    Arnoff, Amanda
    Bloch, Eric
    Rosenthal, Joel
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [5] Efficient and ecofriendly cellulose-supported MIL-100(Fe) for wastewater treatment
    Taherzade, Seyed Dariush
    Abbasichaleshtori, Mehrnaz
    Soleimannejad, Janet
    RSC ADVANCES, 2022, 12 (15) : 9023 - 9035
  • [6] Application of MIL-100(Fe) in drug delivery and biomedicine
    Quijia, Christian Rafael
    Lima, Camila
    Silva, Caroline
    Alves, Renata Carolina
    Frem, Regina
    Chorilli, Marlus
    JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY, 2021, 61
  • [7] Metal organic frameworks MIL-100(Fe) as an efficient adsorptive material for phosphate management
    Nehra, Monika
    Dilbaghi, Neeraj
    Singhal, Nitin Kumar
    Hassan, Ashraf Aly
    Kim, Ki-Hyun
    Kumar, Sandeep
    ENVIRONMENTAL RESEARCH, 2019, 169 : 229 - 236
  • [8] Efficient and effective removal of toluene from aqueous solution using MIL-100(Fe)
    Flores, Catalina V.
    Obeso, Juan L.
    Viltres, Herlys
    Peralta, Ricardo A.
    Ibarra, Ilich A.
    Leyva, Carolina
    ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY, 2024, 10 (09) : 2142 - 2147
  • [9] Tailoring MIL-100(Fe)-derived catalyst for controlled carbon dioxide conversion and product selectivity
    Ahmed, Hany E.
    Albolkany, Mohamed K.
    El-Khouly, Mohamed E.
    El-Moneim, Ahmed Abd
    RSC ADVANCES, 2024, 14 (20) : 13946 - 13956
  • [10] Stable ABTS Immobilized in the MIL-100(Fe) Metal-Organic Framework as an Efficient Mediator for Laccase-Catalyzed Decolorization
    Liu, Youxun
    Geng, Yuanyuan
    Yan, Mingyang
    Huang, Juan
    MOLECULES, 2017, 22 (06):
12345