Synthesis of Isoxazolidines, Isoxazolines and Isoxazoles from O-Unsaturated Alkoxyamines

被引：8
|
作者：
Escudero, Julien [1 ]
Bellosta, Veronique [1 ]
Cossy, Janine [1 ]
机构：
[1] PSL Res Univ, Lab Chim Organ, Inst Chem Biol & Innovat CBI, CNRS,ESPCI Paris, 10 Rue Vauquelin, F-75231 Paris 05, France
来源：
LETTERS IN ORGANIC CHEMISTRY | 2018年 / 15卷 / 05期
关键词：
Alkoxyamine; hydroxylamine; isoxazolidine; isoxazoline; isoxazole; cyclization; synthesis; review; STEREOSELECTIVE-SYNTHESIS; HYDROXYLAMINES; CYCLIZATION; ALCOHOLS; HOMOALLYLHYDROXYLAMINES; REARRANGEMENT; CHEMISTRY; BROMIDES;
D O I：
10.2174/1570178614666171023161721
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
O-Unsaturated alkoxyamines are versatile compounds that can be cyclized to heterocyclic 5-membered rings by using onium ions, transition metals, Bronsted and Lewis acids. O-Allylic and O-homoallylic alkoxyamines can be transformed to isoxazolidines, O-allenyl alkoxyamines to isoxazolidines as well as to 2-isoxazolines and O-alkynyl alkoxyamines to 2-or 3-isoxazolines as well as to isoxazoles.
引用
收藏
页码：365 / 374
页数：10
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