Reductive N-Alkylation of Nitro Compounds to N-Alkyl and N,N-Dialkyl Amines with Glycerol as the Hydrogen Source

被引：66

作者：

Cui, Xinjiang ^{[1
,2
,3
]}

Deng, Youquan ^{[1
]}

Shi, Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[3] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China

来源：

ACS CATALYSIS | 2013年 / 3卷 / 05期

关键词：

amines; alcohols; N-alkylation; glycerol; renewable; catalysis; INTRAMOLECULAR HYDROAMINATION; SELECTIVE SYNTHESIS; SECONDARY ALCOHOLS; AMIDE SYNTHESIS; ARYL HALIDES; RUTHENIUM; EFFICIENT; SULFONAMIDES; NITROARENES; CATALYST;

D O I：

10.1021/cs400049b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

As the sustainable and promising hydrogen source, here glycerol was directly used as the hydrogen source for the reductive amination of alcohol using nitrobenzene as the starting material. The amination of alcohols, especially aliphatic alcohols with different structures, was realized, and mono- or disubstituted amines were synthesized with excellent yields. The reaction mechanism was also explored

引用

页码：808 / 811

页数：4

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