Dissociation of H2 in the energy region at the H(n=1)+H(n=3) dissociation threshold after (1+1′) resonance-enhanced two-photon ionization via the B1Σu+ state

被引：17

作者：

Scheper, CR

de Lange, CA

de Lange, A

Reinhold, E

Ubachs, W

机构：

[1] Univ Amsterdam, Phys Chem Lab, NL-1018 WS Amsterdam, Netherlands

[2] Free Univ Amsterdam, Dept Phys & Astron, NL-1081 HV Amsterdam, Netherlands

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 312卷 / 2-4期

关键词：

D O I：

10.1016/S0009-2614(99)00967-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present a study of the H(n = 1)+ H(n = 3) dissociation process in molecular hydrogen occurring after one-photon absorption from various rovibrational levels (upsilon' = 19,20; J' = 0, I) of the B(1)Sigma(u)(t)(1s sigma(g))(2p sigma(u)) state using (1 + 1') resonance-enhanced multiphoton ionization (REMPI). The results provide further evidence for the importance of the excitation of the vibrational continua of singly excited Rydberg states after one-photon absorption from the B state. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：131 / 138

页数：8

共 50 条

[1] Photoionization and photodissociation dynamics of H2 after (3+1) resonance-enhanced multiphoton ionization via the B 1Σu+ state
Scheper, CR
Buma, WJ
de Lange, CA
van der Zande, WJ
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (19): : 8319 - 8329
[2] Double resonance spectroscopy of the D1Πu+ and B"(B)over-bar1Σu+ states near the third dissociation threshold of H2
Ekey, R. C.
Cordova, A. E.
Duan, W.
Chartrand, A. M.
McCormack, E. F.
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2013, 46 (23)
[3] NON-FRANCK-CONDON VIBRATIONAL DISTRIBUTION IN THE (1+1')-PHOTON RESONANCE-ENHANCED MULTIPHOTON IONIZATION OF H2
KHATUN, J
SANYAL, S
DASTIDAR, KR
PHYSICAL REVIEW A, 1994, 49 (06): : 4765 - 4769
[4] Resonance-enhanced two-photon dissociation of H2 through nonadiabatically coupled intermediate and final states
Datta, A
Saha, S
Bhattacharyya, SS
PHYSICAL REVIEW A, 1999, 60 (02): : 1324 - 1335
[5] Two-photon dissociative photoionization and photodissociation of single H2 B 1Σu+(υ = 5) rotational states
Rudower Chaussee 6, D-12474 Berlin, Germany
J Phys B At Mol Opt Phys, 18 (4049-4064):
[6] Energy and Density Analyses of the 1Σu+ States in the H2 Molecule from the United Atom to Dissociation
Corongiu, Giorgina
Clementi, Enrico
JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (52): : 14791 - 14799
[7] Radiative lifetimes for the B1Σu+ and C1Πu states of the H2 molecule
Pardo, A
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2001, 57 (05) : 1057 - 1060
[8] The effect of electronic autoionization on vibrational branching ratio in (1+1′)-photon resonance-enhanced multiphoton ionization of H2 molecules:: dependence on laser intensity
Khatun, J
Dastidar, KR
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1999, 32 (02) : 373 - 386
[9] On the competition between photoionisation and photodissociation of molecular deuterium after (3+1) resonance-enhanced multiphoton excitation via the B1Σu+ state
Scheper, CR
Somers, MF
de Lange, CA
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2000, 108 (1-3) : 123 - 133
[10] Double resonance spectroscopy of the B"(B)over-bar 1Σu+ state of H2
Ekey, RC
Marks, A
McCormack, EF
PHYSICAL REVIEW A, 2006, 73 (02):

← 1 2 3 4 5 →