Computational study of electrophilic addition to acrylate anion:: cyclic halonium is the transition structure for degenerate rearrangement of α-lactones

被引：6

作者：

Ruggiero, GD ^{[1
]}

Williams, IH ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b200900e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cyclic chloronium or bromonium carboxylate obtained by addition of Cl+ or Br+ to acrylate anion is shown by PCM/ B3LYP/ 6- 31+ G* calculations to be not an intermediate but a transition structure for interconversion of equivalent halomethyl oxiranones.

引用

页码：732 / 733

页数：2