Dynamics and fluxionality in metal carbonyl clusters: Some old and new problems

被引：43
|
作者：
Farrugia, LJ
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 11期
关键词：
D O I：
10.1039/a608514h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This perspective reviews some of the author's recent work on the dynamics and fluxionality of small metal carbonyl clusters. The compounds discussed include [Fe-2(CO)(4)Cp-2] (Cp = eta(5)-C5H5) and the homo- and hetero-metallic clusters in the series [M-3(CO)(12)] (M = Fe, Ru or Os). The front cover shows the space-fill view of the unit cell for [Fe-3(CO)(12)] in the low-temperature phase and illustrates the tightly interlocked packing of the molecules.
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页码：1783 / +
页数：1
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