First Born differential cross-sections for electronic excitation in the helium atom

被引:53
|
作者
Cann, NM
Thakkar, AJ [1 ]
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 6E2, Canada
关键词
helium; electron impact differential cross-sections; elastic and inelastic scattering; first Born approximation; generalized oscillator strengths;
D O I
10.1016/S0368-2048(02)00016-6
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Generalized oscillator strengths for transitions from the ground state of the helium atom to the n(1)S, n(1)P, and n(1)D states with n < 7 are obtained from explicitly correlated wave functions. These results are used to calculate, within the first Born approximation (FBA), elastic and inelastic differential cross-sections for scattering of electrons with impact energies between 100 and 1500 eV. Detailed comparisons between FBA and measured cross-sections are presented. At small angles, the FBA is accurate over a large range of impact energies for the optically allowed transitions to the n(1)P states. The FBA reaches a comparable level of accuracy for optically forbidden transitions only at higher impact energies. The FBA is significantly in error for elastic scattering in the forward direction even at 1500-eV impact energy. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:143 / 159
页数:17
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