Ti-V-Mn based metal hydrides for hydrogen storage

被引：34

作者：

Pickering, Lydia ^{[1
]}

Li, Jing ^{[1
]}

Reed, Daniel ^{[1
]}

Bevan, Alexander I. ^{[1
]}

Book, David ^{[1
]}

机构：

[1] Univ Birmingham, Sch Met & Mat, Birmingham B15 2TT, W Midlands, England

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2013年 / 580卷

基金：

英国工程与自然科学研究理事会;

关键词：

Hydrogen storage materials; Ti-V based alloys; X-ray diffraction; Microstructure; Hydrogen absorption-desorption; LAVES-PHASE ALLOYS; CRYSTAL-STRUCTURE; PRESSURE; VESSEL; DEUTERIDE;

D O I：

10.1016/j.jallcom.2013.03.208

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two Ti-V-Mn BCC-Laves phase alloys with the nominal composition Ti0.5V0.5 +/- xMn (x = -0.04 and 0.01), were synthesised by arc melting. This compositional difference resulted in different compositions and unit cell volumes for the C14 Laves phase. Ti0.47V0.46Mn and Ti0.50V0.51Mn demonstrated reversible hydrogen sorption capacities of 1.53 and 1.56 +/- 0.05 wt.% (at 120 bar H-2 at 303 K) respectively, however, the change in composition results in a small change in the enthalpy of hydride decomposition, and a significant change in plateau pressure and hysteresis. This may allow for the plateau pressure to be tuned to meet the requirements of different solid-state hydrogen storage applications. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：S233 / S237

页数：5

共 50 条

[1] Ti-V-Mn based metal hydrides for hydrogen storage
School of Metallurgy and Materials, University of Birmingham, Birmingham B15 2TT, United Kingdom
Pickering, L. (lydia.pickering@btinternet.com), 1600, Elsevier Ltd (580):
[2] Ti-V-Mn based metal hydrides for hydrogen compression applications
Pickering, Lydia
Reed, Daniel
Bevan, Alexander I.
Book, David
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 645 : S400 - S403
[3] Crystal structure and hydrogen storage properties of Ti-V-Mn alloys
Chen, X. Y.
Chen, R. R.
Ding, X.
Fang, H. Z.
Guo, J. J.
Ding, H. S.
Su, Y. Q.
Fu, H. Z.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (12) : 6210 - 6218
[4] Ti-V-Mn based alloys for hydrogen compression system
Dehouche, Z
Savard, M
Laurencelle, F
Goyette, J
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 400 (1-2) : 276 - 280
[5] Effects of Ti/Mn ratio on microstructure and hydrogen storage properties of Ti-V-Mn alloys
Chen, X.Y. (chenxiaoyuhit@163.com), 2018, Elsevier Ltd (748)
[6] Effects of Ti/Mn ratio on microstructure and hydrogen storage properties of Ti-V-Mn alloys
Chen, R. R.
Chen, X. Y.
Ding, X.
Li, X. Z.
Guo, J. J.
Ding, H. S.
Su, Y. Q.
Fu, H. Z.
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 748 : 171 - 178
[7] Insight into the effect of annealing treatment on hydrogen storage properties of a Ti-V-Mn alloy
Wu, Ran
Li, Ruihan
Ke, Dandan
Zhao, Xin
Hu, Feng
Liu, Jingjing
Zou, Songtao
Zhang, Bo
Zhang, Lu
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2025, 36 : 2118 - 2126
[8] Effect of phase formation on hydrogen storage properties in Ti-V-Mn alloys by zirconium substitution
Chen, X. Y.
Chen, R. R.
Ding, X.
Fang, H. Z.
Li, X. Z.
Ding, H. S.
Su, Y. Q.
Guo, J. J.
Fu, H. Z.
ENERGY, 2019, 166 : 587 - 597
[9] Hydrogen absorption and modulated structure in Ti-V-Mn alloys
Iba, Hideki
Akiba, Etsuo
Journal of Alloys and Compounds, 1997, 253-254 (1-2) : 21 - 24
[10] Hydrogen absorption and modulated structure in Ti-V-Mn alloys
Iba, H
Akiba, E
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 : 21 - 24

← 1 2 3 4 5 →