Initial stage of oxidation of hydrogen-terminated silicon surfaces

被引:43
|
作者
Hattori, T [1 ]
Aiba, T [1 ]
Iijima, E [1 ]
Okube, Y [1 ]
Nohira, H [1 ]
Tate, N [1 ]
Katayama, M [1 ]
机构
[1] SHIN ETU HANDOTAI CO LTD, ANNAKA, GUMMA 37901, JAPAN
关键词
D O I
10.1016/S0169-4332(96)00165-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural changes produced by the oxidation of hydrogen-terminated Si(111)-1 x 1 and Si(100)-2 x 1 surfaces at 300 degrees C in dry oxygen under a pressure of 1 Torr were investigated by X-ray photoelectron spectroscopy (XPS) and multiple internal reflection infrared absorption spectroscopy (MIR-IRAS). Following results are obtained from the analysis and simulation of the experimental results: (1) the layer-by-layer oxidation reaction occurs locally at SiO2/Si(111) interface, while that does not occur at SiO2/Si(100) interface, however, (2) the oxidation on Si(100) surface proceeds more uniformly in atomic scale than that on Si(111) surface.
引用
收藏
页码:323 / 328
页数:6
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