A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing

被引：69
|
作者：
Schmittel, Michael [1 ]
Shu Qinghai [1 ]
机构：
[1] Univ Siegen, Ctr Micro & Nanochem & Engn, D-57068 Siegen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 21期
关键词：
ELECTROGENERATED CHEMILUMINESCENCE; ACETATE ION; CYANIDE; COMPLEXES; SENSOR; WATER; RECOGNITION; RECEPTORS; CHEMISTRY; BORANES;
D O I：
10.1039/c2cc17731e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Iridium complex [(pq)(2)IrCl](2) (1) is established as a quantitatively operating lab-on-a-molecule in aqueous media at physiological pH. Acting as a chemodosimeter, 1 uses two channels, PL and ECL, for the detection of cyanide and acetate, with the former undergoing nucleophilic attack and the latter Kolbe electrolysis and radical-metal combination.
引用
收藏
页码：2707 / 2709
页数：3
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