Model for the DSC thermograms of the melting of ideal binary solutions

In this paper, a model is developed in order to determine the melting thermogram of a binary mixture, presenting a solid solution. Considering the case of an ideal solution, whose enthalpy function is analytically derived, we highlight the large differences existing between the thermogram and the derivative of the enthalpy function. The influence of the heating rates and the mass of the sample are analyzed for different concentrations. Finally, in the case of a thermodynamical equilibrium, we describe how to construct the phase diagram of the solution (liquidus and solidus temperatures, total latent heat). (C) 2013 Elsevier B.V. All rights reserved.