Evolvement of molecular nanomagnets in China

被引:8
|
作者
Wang, Bing-Wu [1 ]
Wang, Xin-Yi [2 ]
Sun, Hao-Ling [3 ]
Jiang, Shang-Da [4 ]
Gao, Song [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[3] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[4] Univ Stuttgart, Inst Phys, D-70550 Stuttgart, Germany
关键词
molecular nanomagnet; single-molecule magnet; single-chain magnet; single-ion magnet; SINGLE-CHAIN MAGNETS; COUPLING DY-3 TRIANGLES; COORDINATION POLYMERS; SURFACE MODIFICATION; ZERO-FIELD; RELAXATION; ANISOTROPY; MAGNETIZATION; CLUSTERS; SYMMETRY;
D O I
10.1098/rsta.2012.0316
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Molecular nanomagnets have been undergoing development for 20 years since the first single-molecule magnet (SMM), Mn12Ac, was characterized as the molecule-behaved magnet. The multi-disciplinary scientists promoted the magnetic characteristics to be more suitable for use in information science and spintronics. The concept of molecular nanomagnets has also evolved to include single-chain magnets (SCMs), single-ion magnets (SIMs) and even magnetic molecules that showed only slow magnetic relaxation, in addition to the initial cluster-type SMMs. In this review, several aspects, including SMMs, SCMs and SIMs, are introduced briefly through some representative examples. In particular, the contribution of Chinese chemists is highlighted in the design, synthesis and understanding of various types of molecular nanomagnets.
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页数:26
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