Metal Organic Framework-Polyethersulfone Composite Membrane for Iodine Capture

被引:19
|
作者
Tang, Po-Hsiang [1 ]
So, Pamela Berilyn [2 ]
Lee, Kueir-Rarn [3 ]
Lai, Yu-Lun [4 ]
Lee, Cheng-Shiuan [4 ]
Lin, Chia-Her [1 ,5 ]
机构
[1] Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan
[2] Chung Yuan Christian Univ, Dept Chem, Taoyuan 32023, Taiwan
[3] Chung Yuan Christian Univ, Dept Chem Engn, R&D Ctr Membrane Technol, Chungli 32023, Taiwan
[4] Ind Technol Res Inst, Green Energy & Environm Res Labs, Hsinchu 31040, Taiwan
[5] Chung Yuan Christian Univ, R&D Ctr Membrane Technol, Taoyuan 32023, Taiwan
关键词
metal organic framework; iodine capture; mixed matrix membranes; MOF-polymer composite; SELECTIVITY; MOF; CONVERSION; SORPTION;
D O I
10.3390/polym12102309
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A variety of metal organic frameworks (MOFs) were synthesized and evaluated for their iodine adsorption capacity. Out of the MOFs tested, ZIF-8 showed the most promising result with an iodine vapor uptake of 876.6 mg/g. ZIF-8 was then incorporated into a polymer, polyethersulfone (PES), at different proportions to prepare mixed matrix membranes (MMMs), which were then used to perform further iodine adsorption experiments. With a mixing ratio of 40 wt % of ZIF-8, the iodine adsorption capacity reached 1387.6 mg/g, wherein an astounding 60% improvement in adsorption was seen with the MMMs prepared compared to the original ZIF-8 powder.
引用
收藏
页码:1 / 15
页数:15
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