Properties and preparation of porous carbon material supported with modified TiO2

被引:4
|
作者
Liu, Chengbao [1 ,2 ]
Chen, Zhigang [1 ,2 ,3 ,4 ]
Miao, Zhi [3 ]
Chen, Feng [1 ,2 ,3 ]
Gu, Cheng [3 ]
Huang, Minqi [1 ]
Zhao, Xiaobing [5 ]
机构
[1] Suzhou Univ Sci & Technol, Dept Chem & Bioengn, Suzhou 215009, Peoples R China
[2] Suzhou Univ Sci & Technol, Jiangsu Key Lab Environm Funct Mat, Suzhou 215009, Peoples R China
[3] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
[4] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[5] Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R China
来源
关键词
Titania; Porous carbon based adsorption material; Ceria; Surface modification; Adsorption and photocatalytic synergistic effect; ACTIVATED CARBONS;
D O I
10.1016/j.proeng.2011.12.487
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Titania (P25-type) was used as photocatalytic matrix, and ceria was introduced to modify P25 by a deposit method in order to improve the photocatalytic property. Recombination of charge carriers have been restrained by the oxygen storage effect of rare earth elements. Modified P25 (CeO2/TiO2) has been proved to be more effective in photocatalytic application by fluorescence spectrum. Then CeO2/TiO2 was wrapped on the surface of expanded graphite-amorphous carbon (EGC) to form a new kind of carbon based composite-adsorption and photocatalytic integration material (CTO/EGC). With a large amount of micropores on the surface, the specific surface area could reach 963m(2)/g, and the composite has a benefit in little molecular organic pollutants adsorption. With a synergistic effect of adsorption and photocatalytic, 100mL methyl orange with the concentration of 50mg/L could be effectively decomposed by 100mg CTO/EGC, up to 96% after 3 hours. (C) 2011 Published by Elsevier Ltd.
引用
收藏
页码:557 / 563
页数:7
相关论文
共 14 条
  • [1] Activated carbons by pyrolysis of coffee bean husks in presence of phosphoric acid
    Baquero, MC
    Giraldo, L
    Moreno, JC
    Suárez-García, F
    Martínez-Alonso, A
    Tascón, JMD
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2003, 70 (02) : 779 - 784
  • [2] [陈志波 Chen Zhibo], 2010, [河海大学学报. 自然科学版, Journal of Hohai University. Natural Sciences], V38, P704
  • [3] Intrinsic Hole Migration Rates in TiO2 from Density Functional Theory
    Deskins, N. Aaron
    Dupuis, Michel
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (01): : 346 - 358
  • [4] Interfacial and surface structures of CeO2-TiO2 mixed oxides
    Fang, Jun
    Bao, Huizhi
    He, Bo
    Wang, Fang
    Si, Dejun
    Jiang, Zhiquan
    Pan, Zhiyun
    Wei, Shiqiang
    Huang, Weixin
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (51): : 19078 - 19085
  • [5] Time-resolved photoluminescence of particulate TiO2 photocatalysts suspended in aqueous solutions
    Fujihara, K
    Izumi, S
    Ohno, T
    Matsumura, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 132 (1-2) : 99 - 104
  • [6] Analysis of the micropore structure of various microporous materials from nitrogen adsorption at 77 K
    Gil, A
    [J]. ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 1998, 4 (3-4): : 197 - 206
  • [7] Jian PM, 2001, CHINESE J CATAL+, V22, P161
  • [8] Preparation and photocatalytic activity of CeO2/TiO2 interface composite film
    Jiang, Bangtong
    Zhang, Shengyi
    Guo, Xiaozhu
    Jin, Baokang
    Tian, Yupeng
    [J]. APPLIED SURFACE SCIENCE, 2009, 255 (11) : 5975 - 5978
  • [9] Visible light photodegradation of 4-chlorophenol with a coke-containing titanium dioxide photocatalyst
    Lettmann, C
    Hildenbrand, K
    Kisch, H
    Macyk, W
    Maier, WF
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2001, 32 (04) : 215 - 227
  • [10] Association of activated carbons of different origins with titania in the photocatalytic purification of water
    Matos, J
    Laine, J
    Herrmann, JM
    [J]. CARBON, 1999, 37 (11) : 1870 - 1872