Products of anodic oxidation of carbamide: Effect of anionic composition of solution

被引：5

作者：

Osetrova, NV ^{[1
]}

Skundin, AM ^{[1
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Electrochem, Moscow 117071, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2002年 / 38卷 / 03期

关键词：

Oxidation; Sulfate; Nitrate; Carbamide; Platinum;

D O I：

10.1023/A:1014730723071

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The current efficiency for carbamide oxidation on smooth platinum electrode to molecular nitrogen and nitrate in sulfate, fluoride, chloride, and bromide solutions are determined. The supporting-electrolyte anion has a complex effect on the ratio between rates of these processes. Independence of the current efficiency from the solution pH in electrolysis of sulfate solutions of carbamide is confirmed.

引用

页码：266 / 269

页数：4

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