Preparation and characterization of {3-[2-Pd(mu-Cl)-4-MeO-C6H3-]syd-P(Bu-t)(2)}(2)

被引：12

作者：

Lin, ST ^{[1
]}

Cheo, HS ^{[1
]}

Liu, LS ^{[1
]}

Wang, JC ^{[1
]}

机构：

[1] SOOCHOW UNIV,DEPT CHEM,TAIPEI 11101,TAIWAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 08期

关键词：

D O I：

10.1021/om960728h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dimer of a six-membered metallacycle [Pd-(C-P)X](2) (2) was prepared by reacting PdCl2 with 3-(4-methoxyphenyl-4-(di-tert-butylphosphino)sydnone in an ethanol solution at 80 degrees C. This is the first report of the activation of a C-H bond in the arylsydnone system. The molecular structure of compound 2 was determined by a single-crystal X-ray crystallographic study.

引用

页码：1803 / 1805

页数：3

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