Effect of benzothiophene on tetralin hydrogenation over supported rhodium catalyst in supercritical carbon dioxide solvent

被引:1
|
作者
Hiyoshi, Norihito [1 ]
Rode, Chandrashekhar V. [1 ]
Sato, Osamu [1 ]
Shirai, Masayuki [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Compact Chem Proc, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
Supercritical carbon dioxide; hydrogenation; tetralin; cis-decalin;
D O I
10.1007/BF03036936
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrogenation behavior of tetralin in the presence and absence of benzothiophene was studied over a charcoal-supported rhodium catalyst in supercritical carbon dioxide solvent. The catalyst activity, as well as cis-decalin selectivity, decreased in the presence of benzothiophene.
引用
收藏
页码:767 / 770
页数:4
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