The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications

被引：297

作者：

Giustra, Zachary X. ^{[1
]}

Liu, Shih-Yuan ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 04期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

LATE-STAGE FUNCTIONALIZATION; RING-EXPANSION REACTION; HETEROAROMATIC-COMPOUNDS; B-N; BROMINATED 2,1-BORAZARONAPHTHALENES; CROSS-COUPLINGS; AZO DYES; C-C; BOROLES; NAPHTHALENE;

D O I：

10.1021/jacs.7b09446

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Boron-nitrogen heteroarenes hold great promise for practical application in many areas of chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation with respect to these compounds' synthesis. This Perspective discusses in detail the most recent advances in methods pertaining to the preparation of BN-isosteres of benzene, naphthalene, and their derivatives. Additional focus is placed on the progress enabled by these syntheses toward functional utility of such BN-heterocycles in biochemistry and pharmacology, materials science, and transition-metal-based catalysis. The prospects for future research efforts in these and related fields are also assessed.

引用

页码：1184 / 1194

页数：11

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