Selective acid-functionalized mesoporous silica catalyst for conversion of glycerol to monoglycerides: state of the art and future prospects

被引:15
|
作者
Hermida, Lilis [1 ,2 ]
Amani, Hadis [1 ]
Saeidi, Samrand [3 ,4 ]
Abdullah, Ahmad Zuhairi [1 ]
Mohamed, Abdul Rahman [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Penang, Malaysia
[2] Univ Lampung, Dept Chem Engn, Bandar Lampung 35145, Lampung, Indonesia
[3] AREEO, Res Inst Forests & Rangelands, Dept Wood & Paper Sci, Tehran, Iran
[4] Amirkabir Univ Technol, Tehran Polytech, Sch Chem Engn, 424 Hafez Ave, Tehran 15914, Iran
关键词
acid functionalization; mesoporous catalyst; reaction phenomena; selective esterification of monoglyceride; synthesis procedure; POST-SYNTHESIS ALUMINATION; FRIEDEL-CRAFTS ACYLATION; MOLECULAR-SIEVES; SULFATED ZIRCONIA; FATTY-ACIDS; LAURIC ACID; EFFICIENT CATALYST; OLEIC-ACID; ACTIVE-SITES; PORE-SIZE;
D O I
10.1515/revce-2016-0039
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The quest for efficient and selective catalysts for conversion of glycerol monoglyceride is critical for the development of reliable methods for its synthesis. Thus, various types of catalyst and methods of catalyst manufacturing for conversion of glycerol to monoglycerides have been investigated. Acid-functionalized mesoporous catalysts are emerging as highly efficient catalysts for conversion of glycerol into monoglyceride. The incorporation of acid components into different mesoporous silicas for this application is reviewed in this work. The superiority of mesostructure catalysts in comparison to microporous catalysts has been elucidated in terms of accessibility to active sites, pore diffusion, thermal stability of the catalyst and catalyst reusability. Recent direction of novel acid-functionalized mesoporous catalysts development for this application is also critically reviewed.
引用
收藏
页码:239 / 265
页数:27
相关论文
共 50 条
  • [1] Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production
    Vinayak Hegde
    Parimal Pandit
    Pranita Rananaware
    Varsha P.Brahmkhatri
    Frontiers of Chemical Science and Engineering, 2022, 16 (08) : 1198 - 1210
  • [2] Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production
    Vinayak Hegde
    Parimal Pandit
    Pranita Rananaware
    Varsha P. Brahmkhatri
    Frontiers of Chemical Science and Engineering, 2022, 16 : 1198 - 1210
  • [3] Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production
    Hegde, Vinayak
    Pandit, Parimal
    Rananaware, Pranita
    Brahmkhatri, Varsha P.
    FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING, 2022, 16 (08) : 1198 - 1210
  • [4] Catalytic Conversion of Glycerol to Lactic Acid: State of the Art and Prospects
    S. A. Zavrazhnov
    A. L. Esipovich
    S. M. Danov
    S. Yu. Zlobin
    A. S. Belousov
    Kinetics and Catalysis, 2018, 59 : 459 - 471
  • [5] Catalytic Conversion of Glycerol to Lactic Acid: State of the Art and Prospects
    Zavrazhnov, S. A.
    Esipovich, A. L.
    Danov, S. M.
    Zlobin, S. Yu
    Belousov, A. S.
    KINETICS AND CATALYSIS, 2018, 59 (04) : 459 - 471
  • [6] Arenesulfonic Acid-Functionalized Bentonite as Catalyst in Glycerol Esterification with Acetic Acid
    Tangestanifard, Maryam
    Ghaziaskar, Hassan S.
    CATALYSTS, 2017, 7 (07):
  • [7] Efficient enrichment of glycopeptides with sulfonic acid-functionalized mesoporous silica
    Bibi, Aisha
    Ju, Huangxian
    TALANTA, 2016, 161 : 681 - 685
  • [8] Sulfonic acid-functionalized mesoporous silica nanoparticles (SAMSNs): a recoverable heterogeneous acid catalyst for green synthesis of dicoumarols
    Ebrahim Mehrasbi
    Yaghoub Sarrafi
    Amir Vahid
    Heshmatollah Alinezhad
    Research on Chemical Intermediates, 2015, 41 : 4929 - 4941
  • [9] Sulfonic acid-functionalized mesoporous silica nanoparticles (SAMSNs): a recoverable heterogeneous acid catalyst for green synthesis of dicoumarols
    Mehrasbi, Ebrahim
    Sarrafi, Yaghoub
    Vahid, Amir
    Alinezhad, Heshmatollah
    RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (07) : 4929 - 4941
  • [10] Sulfonic acid-functionalized mesoporous carbon/silica as efficient catalyst for dehydration of fructose into 5-hydroxymethylfurfural
    Tian, Xiaoning
    Jiang, Zhongqing
    Jiang, Yingying
    Xu, Weitong
    Li, Chenxu
    Luo, Lijuan
    Jiang, Zhong-Jie
    RSC ADVANCES, 2016, 6 (103): : 101526 - 101534