Imaging molecular isomerization using molecular-frame photoelectron angular distributions

被引：22

作者：

Rescigno, T. N. ^{[1
]}

Douguet, Nicolas ^{[2
]}

Orel, A. E. ^{[2
]}

机构：

[1] Univ Calif Berkeley, Chem Sci & Ultrafast Xray Sci Lab, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA

[2] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA

来源：

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 2012年 / 45卷 / 19期

关键词：

ION;

D O I：

10.1088/0953-4075/45/19/194001

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We report the results of an ab initio theoretical study of K-shell photoionization of the monocation of acetylene in its ground (X) and electronically excited (A) states using the complex Kohn variational method. We show how the molecular-frame photoelectron angular distributions, which are sensitive to the instantaneous positions of the nuclei, can be used to monitor the isomerization of the excited cation from an initial linear geometry to a final vinylidene-like structure.

引用

页数：6

共 50 条

[1] Molecular-frame photoelectron angular distributions
Lucchese, Robert R.
Stolow, Albert
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2012, 45 (19)
[2] Probing gaseous molecular structure by molecular-frame photoelectron angular distributions
Fukuzawa, Hironobu
Yamada, Syuhei
Sakakibara, Yuta
Tachibana, Tetsuya
Ito, Yuta
Takanashi, Tsukasa
Nishiyama, Toshiyuki
Sakai, Tsukasa
Nagaya, Kiyonobu
Saito, Norio
Oura, Masaki
Stener, Mauro
Decleva, Piero
Ueda, Kiyoshi
JOURNAL OF CHEMICAL PHYSICS, 2019, 151 (10):
[3] Imaging molecular shapes with molecular-frame photoelectron angular distributions from core hole ionization
Trevisan, C. S.
McCurdy, C. W.
Rescigno, T. N.
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2012, 45 (19)
[4] Probing molecular bond-length using molecular-frame photoelectron angular distributions
Fukuzawa, Hironobu
Lucchese, Robert R.
Liu, Xiao-Jing
Sakai, Kentaro
Iwayama, Hiroshi
Nagaya, Kiyonobu
Kreidi, Katharina
Schoeffler, Markus S.
Harries, James R.
Tamenori, Yusuke
Morishita, Yuichiro
Suzuki, Isao H.
Saito, Norio
Ueda, Kiyoshi
JOURNAL OF CHEMICAL PHYSICS, 2019, 150 (17):
[5] Molecular-frame photoelectron and electron-frame photoion angular distributions and their interrelation
Liu, X-J
Lucchese, R. R.
Grum-Grzhimailo, A. N.
Morishita, Y.
Saito, N.
Prumper, G.
Ueda, K.
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2007, 40 (03) : 485 - 496
[6] Time-resolved molecular-frame photoelectron angular distributions: Snapshots of acetylene-vinylidene cationic isomerization
Douguet, N.
Rescigno, T. N.
Orel, A. E.
PHYSICAL REVIEW A, 2012, 86 (01):
[7] High-energy molecular-frame photoelectron angular distributions: a molecular bond-length ruler
Vela-Perez, I.
Ota, F.
Mhamdi, A.
Tamura, Y.
Rist, J.
Melzer, N.
Uerken, S.
Nalin, G.
Anders, N.
You, D.
Kircher, M.
Janke, C.
Waitz, M.
Trinter, F.
Guillemin, R.
Piancastelli, M. N.
Simon, M.
Davis, V. T.
Williams, J. B.
Doerner, R.
Hatada, K.
Yamazaki, K.
Fehre, K.
Demekhin, Ph. V.
Ueda, K.
Schoeffler, M. S.
Jahnke, T.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (19) : 13784 - 13791
[8] Relationship between polarization-averaged molecular-frame photoelectron angular distributions and geometry
Plesiat, Etienne
Decleva, Piero
Martin, Fernando
PHYSICAL REVIEW A, 2013, 88 (06):
[9] Molecular-Frame Photoelectron Angular Distributions of CO in the Vicinity of Feshbach Resonances: An XCHEM Approach
Borras, Vicent J.
Gonzalez-Vazquez, Jesus
Argenti, Luca
Martin, Fernando
JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2021, 17 (10) : 6330 - 6339
[10] Discrimination of Excited States of Acetylacetone through Theoretical Molecular-Frame Photoelectron Angular Distributions
Ponzi, Aurora
Sapunar, Marin
Doslic, Nadja
Decleva, Piero
MOLECULES, 2022, 27 (06):

← 1 2 3 4 5 →