Removal of phosphite and sulfate from electroless nickel-phosphorus plating bath with hydrotalcite for the management of watershed

被引:5
|
作者
Kamimoto, Yuki [1 ]
Ichino, Ryoichi [1 ]
Kiso, Yoshiaki [2 ]
Hosotani, Takuya [3 ]
Kwon, Koo-Ho [4 ]
Min, Kyung-Sok [4 ]
Jung, Yong-Jun [5 ]
机构
[1] Nagoya Univ, EcoTopia Sci Inst, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[2] Toyohashi Univ Technol, Dept Environm & Life Sci, Toyohashi, Aichi 4418580, Japan
[3] TOHKEMY Corp, Taitou Ku, Tokyo, Japan
[4] Kyungpook Natl Univ, Dept Environm Engn, Taegu 702701, South Korea
[5] Catholic Univ Pusan, Dept Environm Engn, Pusan 609757, South Korea
关键词
Hydrotalcite; Phosphorus recovery; Electroless Ni-P plating; IRON-OXIDE HYDROXIDE; SYNTHETIC HYDROTALCITE; EXCHANGE PROPERTIES; ADSORPTIVE REMOVAL; ION-EXCHANGE; WASTE-WATER; RECOVERY;
D O I
10.1080/19443994.2013.781100
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study was focused to remove both HPO32- and SO42- for the improvement of efficiency in electroless nickel- phosphorus plating process with hydrotalcite- like compound ( HT). The adsorbed amount, q(e), of H2PO2- which was main component was low and H2PO2- had little influence on the adsorption of HPO32- and SO42-. HPO32- and SO42- were similar in the adsorption behaviors of the adsorption isotherm and the influence of solution pH. The q(e) was increased with the increase of water temperature, because the CO32- was decreased with the increase of water temperature. On the coexisting adsorption, the q(e) of HPO32- was decreased with SO42-. The ion selectivity of HT was in the order of SO42- > HPO32- > PO43- >> H2PO2- at pH 10. The results indicated that the HT- Cl is a useful adsorbent for HPO32- and SO42- removal in the exhausted electroless nickel- phosphorous plating bath.
引用
收藏
页码:4050 / 4055
页数:6
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