Hysteretic behavior of Fe(phen)2(NCS)2 spin-transition microparticles vs. the environment: A huge reversible component resolved by first order reversal curves
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Tanasa, Radu
[1
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Laisney, Jerome
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Univ Paris 11, UMR CNRS 8182, ECI, ICMMO, F-91405 Orsay, FranceAlexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, Romania
Laisney, Jerome
[2
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Stancu, Alexandru
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Alexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, RomaniaAlexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, Romania
Stancu, Alexandru
[1
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Boillot, Marie-Laure
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Univ Paris 11, UMR CNRS 8182, ECI, ICMMO, F-91405 Orsay, FranceAlexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, Romania
Boillot, Marie-Laure
[2
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Enachescu, Cristian
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Alexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, RomaniaAlexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, Romania
Enachescu, Cristian
[1
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机构:
[1] Alexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, Romania
[2] Univ Paris 11, UMR CNRS 8182, ECI, ICMMO, F-91405 Orsay, France
We discuss the influence of the embedding matrix on the thermal hysteretic behavior of spin transition microparticles of Fe(phen)(2)(NCS)(2) by using a series of experimental first order reversal curves (FORCs). The shape of FORCs supports the hypothesis considering additional interactions between the spin-transition microparticles and the embedding matrix, which compares to a negative pressure on the particles. A mean-field approach based on negative variable external pressures, together with a cut off/switch on of particles-matrix interactions accounts for the experimental features. (C) 2014 AIP Publishing LLC.
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Univ Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, FranceUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France
Linares, Jorge
Varret, Francois
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Univ Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, FranceUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France
Varret, Francois
Codjovi, Epiphane
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Univ Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, FranceUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France
Codjovi, Epiphane
Slimani, Ahmed
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Univ Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, FranceUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France
Slimani, Ahmed
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Tanasa, Radu
Enachescu, Cristian
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Alexandru Ioan Cuza Univ, Dept Phys, Fac Phys, R-700506 Iasi, RomaniaUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France
Enachescu, Cristian
Stancu, Alexandru
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Alexandru Ioan Cuza Univ, Dept Phys, Fac Phys, R-700506 Iasi, RomaniaUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France
Stancu, Alexandru
Haasnoot, Jaap
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Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, NetherlandsUniv Versailles, Grp Etude Mat Condensee, CNRS, UMR 8635, F-78035 Versailles, France