Hysteretic behavior of Fe(phen)2(NCS)2 spin-transition microparticles vs. the environment: A huge reversible component resolved by first order reversal curves

被引:28
|
作者
Tanasa, Radu [1 ]
Laisney, Jerome [2 ]
Stancu, Alexandru [1 ]
Boillot, Marie-Laure [2 ]
Enachescu, Cristian [1 ]
机构
[1] Alexandru Ioan Cuza Univ, Fac Phys, Iasi 700506, Romania
[2] Univ Paris 11, UMR CNRS 8182, ECI, ICMMO, F-91405 Orsay, France
关键词
THERMAL HYSTERESIS; FORC METHOD; CROSSOVER; NANOPARTICLES; PRESSURE; COOPERATIVITY; PHASES;
D O I
10.1063/1.4862748
中图分类号
O59 [应用物理学];
学科分类号
摘要
We discuss the influence of the embedding matrix on the thermal hysteretic behavior of spin transition microparticles of Fe(phen)(2)(NCS)(2) by using a series of experimental first order reversal curves (FORCs). The shape of FORCs supports the hypothesis considering additional interactions between the spin-transition microparticles and the embedding matrix, which compares to a negative pressure on the particles. A mean-field approach based on negative variable external pressures, together with a cut off/switch on of particles-matrix interactions accounts for the experimental features. (C) 2014 AIP Publishing LLC.
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页数:5
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