Ruthenium Complexes with Cooperative CNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane

被引：270
|
作者：
Kaess, Martina [1 ]
Friedrich, Anja [1 ]
Drees, Markus [1 ]
Schneider, Sven [1 ]
机构：
[1] Tech Univ Munich, Dept Chem, D-85748 Garching, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 05期
关键词：
cooperative effects; dehydrogenation; pi interactions; PNP ligands; ruthenium; BORON-NITROGEN BONDS; HYDROGENATION; MECHANISM; AMINOBORANES; GENERATION; BORAZINES; ALCOHOLS; ADDUCTS; KETONES; ROUTE;
D O I：
10.1002/anie.200805108
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) G"Ru"vy reactivity: The new ruthenium(II) complex having cooperative PNP enamido ligand A reversibly activates two equivalents H2 under reversible hydrogenation of amido (B) and amino (C) complexes. B exhibits the highest reported activities in the dehydrocoupling of ammonia-borane. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：905 / 907
页数：3
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