Crystal structure of [(C6H4)P][Ni(B9C2H11)2]•CCl4

被引：2
|
作者：
Polyanskaya, T. M. [1 ]
Drozdova, M. K. [1 ]
Volkov, V. V. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 49卷 / 03期
关键词：
metal derivative of ortho-carborane(12); nickel(III) bisdicarbollyl anion; tetraphenylphosphonium; synthesis; molecular and crystal structure;
D O I：
10.1007/s10947-008-0076-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound containing the tetraphenylphosphonium cation and the nickel(III) bisdicarbollyl anion, [(C6H5)(4)P][Ni(B9C2H11)(2)]center dot CCl4, was synthesized and investigated by XRD at room temperature (295 K). Crystal data: C29H42B18PCl4Ni, M=816.69, monoclinic, space group P2/c; unit cell parameters a = 13.5873(6) angstrom, b = 7.1475(2) angstrom, c = 20.7829(8) angstrom, beta = 94.4595(13)degrees, V = 2012.2(2) angstrom(3), Z = 2, d(calc) = 1.348 g/cm(3). The structure was solved by direct and Fourier methods and refined by the full-matrix least squares method in an anisotropic (isotropic for H) approximation to the final R-1 = 0.0466 for 3055 I-hkl >= 2 sigma(I) of 23,655 reflections collected and 5618 independent I-hkl (Bruker X8 APEX diffractometer lambda MoK alpha).
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页码：560 / 565
页数：6
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