Preparation of Dye-Adsorbing ZnO Thin Films by Electroless Deposition and Their Photoelectrochemical Properties

被引:10
|
作者
Nagaya, Satoshi [1 ]
Nishikiori, Hiromasa [2 ]
机构
[1] Nagano Prefecture Gen Ind Technol Ctr, Okaya, Nagano 3940084, Japan
[2] Shinshu Univ, Dept Environm Sci & Technol, Fac Engn, Nagano 3808553, Japan
关键词
ZnO; thin film; eosin Y; electroless deposition; photoelectric conversion; photoelectrochemistry; ZINC-OXIDE FILMS; AQUEOUS-SOLUTIONS; ELECTRODEPOSITION;
D O I
10.1021/am4026483
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Dye-adsorbing ZnO thin films were prepared on ITO films by electroless deposition. The films were formed in an aqueous solution containing zinc nitrate, dimethylamine-borane, and eosin Y at 328 K. The film thickness was 1.2-2.0 mu m. Thinner and larger-plane hexagonal columns were produced from the solution containing a higher concentration of eosin Y. A photocurrent was observed in the electrodes containing such ZnO films during light irradiation. The photoelectrochemical performance of the film was improved by increasing the concentration of eosin Y because of increases in the amount of absorbed photons and the electronic conductivity of ZnO.
引用
收藏
页码:8841 / 8844
页数:4
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