Room Temperature Oxidation of the Surface of Highly Oriented Pyrolytic Graphite (HOPG) with Nitrogen Dioxide in the Presence of Supported Palladium Particles

被引：6
|
作者：
Smirnov, M. Yu. [1 ]
Kalinkin, A. V. [1 ]
Sorokin, A. M. [1 ]
Bukhtiyarov, V. I. [1 ]
机构：
[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
来源：
KINETICS AND CATALYSIS | 2020年 / 61卷 / 04期
关键词：
palladium; highly oriented pyrolytic graphite (HOPG); NO2; X-ray photoelectron spectroscopy (XPS); X-RAY PHOTOELECTRON; IN-SITU XPS; PLATINUM PARTICLES; PD NANOPARTICLES; GRAPHENE OXIDE; THERMAL-STABILITY; PD(111) OXIDATION; OXYGEN; SIZE; MODEL;
D O I：
10.1134/S0023158420040126
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The interaction of palladium nanoparticles (average size, similar to 3 nm) deposited on the surface of highly oriented pyrolytic graphite (HOPG) with nitrogen dioxide at room temperature and a pressure of 10(-6)or 10(-5)mbar was studied by X-ray photoelectron spectroscopy (XPS). It was shown that the structure of several surface graphene layers was destroyed under these conditions due to the oxidation of carbon at the interface between Pd and HOPG. The reaction proceeded with the participation of oxygen atoms, which were formed as a result of the dissociation of NO(2)molecules on the palladium surface. Palladium particles retained their metallic nature, but they penetrated deep into graphite in this case.
引用
收藏
页码：637 / 645
页数：9
相关论文
共 41 条
  • [1] Room Temperature Oxidation of the Surface of Highly Oriented Pyrolytic Graphite (HOPG) with Nitrogen Dioxide in the Presence of Supported Palladium Particles
    M. Yu. Smirnov
    A. V. Kalinkin
    A. M. Sorokin
    V. I. Bukhtiyarov
    Kinetics and Catalysis, 2020, 61 : 637 - 645
  • [2] Room-Temperature Interaction of Nitrogen Dioxide with Rhodium Nanoparticles Supported on the Surface of Highly Oriented Pyrolytic Graphite (HOPG)
    Smirnov, M. Yu
    Kalinkin, A., V
    Salanov, A. N.
    Sorokin, A. M.
    Bukhtiyarov, V., I
    KINETICS AND CATALYSIS, 2021, 62 (05) : 664 - 674
  • [3] Room-Temperature Interaction of Nitrogen Dioxide with Rhodium Nanoparticles Supported on the Surface of Highly Oriented Pyrolytic Graphite (HOPG)
    M. Yu. Smirnov
    A. V. Kalinkin
    A. N. Salanov
    A. M. Sorokin
    V. I. Bukhtiyarov
    Kinetics and Catalysis, 2021, 62 : 664 - 674
  • [4] Room Temperature Interaction of NO2 with Palladium Nanoparticles Supported on a Nonactivated Surface of Highly Oriented Pyrolytic Graphite (HOPG)
    Smirnov, M. Yu
    Kalinkin, A., V
    Sorokin, A. M.
    Bukhtiyarov, V., I
    KINETICS AND CATALYSIS, 2020, 61 (06) : 907 - 911
  • [5] Room Temperature Interaction of NO2 with Palladium Nanoparticles Supported on a Nonactivated Surface of Highly Oriented Pyrolytic Graphite (HOPG)
    M. Yu. Smirnov
    A. V. Kalinkin
    A. M. Sorokin
    V. I. Bukhtiyarov
    Kinetics and Catalysis, 2020, 61 : 907 - 911
  • [6] Electrochemical intercalation and oxidation of glyoxylic acid into a highly oriented pyrolytic graphite (HOPG) electrode
    Velasco, JG
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (6-8) : 859 - 865
  • [7] A Kinetic and AFM Study of the Electrodeposition of Palladium Nanoclusters onto Highly Oriented Pyrolytic Graphite (HOPG)
    L. H. Mendoza-Huizar
    D. Garrido-Márquez
    C. H. Rios-Reyes
    M. Rivera
    E. García-Sánchez
    C. Galán-Vidal
    Journal of Cluster Science, 2015, 26 : 337 - 346
  • [8] A Kinetic and AFM Study of the Electrodeposition of Palladium Nanoclusters onto Highly Oriented Pyrolytic Graphite (HOPG)
    Mendoza-Huizar, L. H.
    Garrido-Marquez, D.
    Rios-Reyes, C. H.
    Rivera, M.
    Garcia-Sanchez, E.
    Galan-Vidal, C.
    JOURNAL OF CLUSTER SCIENCE, 2015, 26 (02) : 337 - 346
  • [9] Palladium Nanoparticles Supported on Highly Oriented Pyrolytic Graphite: Preparation, Reactivity and Stability
    Ju, Wenbo
    Bruelle, Tine
    Favaro, Marco
    Perini, Lorenzo
    Durante, Christian
    Schneider, Oliver
    Stimming, Ulrich
    CHEMELECTROCHEM, 2015, 2 (04): : 547 - 558
  • [10] Structure control of Pt-Sn bimetallic catalysts supported on highly oriented pyrolytic graphite (HOPG)
    Yao, Yunxi
    Fu, Qiang
    Zhang, Zhen
    Zhang, Hui
    Ma, Teng
    Tan, Dali
    Bao, Xinhe
    APPLIED SURFACE SCIENCE, 2008, 254 (13) : 3808 - 3812
12345