Reactions of a [1],[1]Disilamolybdenocenophane with Unsaturated Compounds

被引：3

作者：

Arnold, Thomas ^{[1
]}

Braunschweig, Holger ^{[1
]}

Hupp, Florian ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Sen, Sakya S. ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 2013卷 / 28期

关键词：

Metallocenes; Molybdenum; Silicon; X-ray diffraction; Coordination modes; RING-OPENING POLYMERIZATION; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; STRAINED METALLOCENOPHANES; ORGANOMETALLIC RINGS; COMPLEXES; REACTIVITY; 1ST; MOLYBDENUM; ACTIVATION;

D O I：

10.1002/ejic.201300766

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of a [1],[1]disilamolybdenocenophane (1) towards several unsaturated substrates has been studied. Treatment of 1 with N-heterocyclic carbene afforded an ansa-metallocene carbene complex. The cleavage of the P=S bond of a phosphane sulfide was observed, resulting in the incorporation of sulfur into the disila-bridging unit and coordination of the phosphane moiety to Mo. Reactions of 1 with carbodiimide and phosphaalkyne led to side-on coordinated products. All products were fully characterized by multinuclear NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction studies.

引用

页码：5027 / 5032

页数：6

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