Are nanojars unique to copper? Solution and solid state characterization of high-symmetry octanuclear nickel(II)-pyrazolate complexes

被引：9

作者：

Al Isawi, Wisam A. ^{[1
]}

Ahmed, Basil M. ^{[1
]}

Hartman, Christian K. ^{[1
]}

Seybold, Alexandria N. ^{[1
]}

Mezei, Gellert ^{[1
]}

机构：

[1] Western Michigan Univ, Dept Chem, Kalamazoo, MI 49008 USA

来源：

INORGANICA CHIMICA ACTA | 2018年 / 475卷

基金：

美国国家科学基金会;

关键词：

TRIGONAL-PRISMATIC GEOMETRY; METAL-ORGANIC FRAMEWORKS; POTASSIUM IRON SULFIDE; X-RAY; CRYSTAL-STRUCTURES; NICKEL(II) COMPLEXES; ELECTRONIC-STRUCTURE; MAGNETIC-PROPERTIES; CLUSTER COMPOUNDS; CUBIC CLUSTERS;

D O I：

10.1016/j.ica.2017.08.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A comprehensive study using sixteen different metal ions was conducted, in order to test the possibility of substituting one or more Cu2+ ions in nanojars, [anion subset of{Cu(mu-OH)(mu-pz)}(n)](2) (n = 27-32; anion = CO32 or SO42 ), with Zn2+, Ni2+, Co2+, Fe2+, Fe3+, Mn2+, Cr3+, VO2+, Cd2+, Ag+, Pd2+, Ce4+, Sn2+, Pb2+, Pr3+ or Nd3+. An octanuclear nickel complex was isolated in the case of Ni2+, which inspired the synthesis of a series of (Bu4N)(2)[Ni-8(mu(4)-OH)(6)(mu-4-Rpz)(12)] (R = H, Me, (n)Oct) complexes. Characterization was carried out in the solid state by X-ray crystallography and thermogravimetric analysis, and, for the first time for this type of complexes, in solution phase by variable-temperature H-1 NMR spectroscopy, UV-vis spectroscopy and electrospray-ionization mass spectrometry. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：65 / 72

页数：8

共 50 条

[1] Copper(II) complexes with lactamides: solution and solid state studies
Tounsi, N
Dupont, L
Mohamadou, A
Cadiou, C
Aplincourt, M
Plantier-Royon, R
Massicot, F
Portella, C
NEW JOURNAL OF CHEMISTRY, 2004, 28 (07) : 785 - 792
[2] Histaminol and Its Complexes with Copper(II) - Studies in Solid State and Solution
Maslewski, Piotr
Wyrzykowski, Dariusz
Witwicki, Maciej
Dolega, Anna
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (12) : 1399 - 1408
[3] Relationship between solid state structure and solution stability of copper(II)-hydroxypyridinecarboxylate complexes
May, Nora V.
Gal, G. Tamas
Szentendrei, Zsolt
Korecz, Laszlo
May, Zoltan
Ferlin, Maria Grazia
Dean, Annalisa
Bombicz, Petra
Di Marco, Valerio B.
NEW JOURNAL OF CHEMISTRY, 2019, 43 (27) : 10699 - 10710
[4] STEREOISOMERISM IN THE NICKEL(II) COMPLEXES OF A CHIRAL TRIDENTATE LIGAND - SOLID-STATE AND SOLUTION STUDY
COSTES, JP
DAHAN, F
DOMINGUEZVERA, JM
LAURENT, JP
RUIZ, J
SOTIROPOULOS, J
INORGANIC CHEMISTRY, 1994, 33 (18) : 3908 - 3913
[5] Solid and solution state flexibility of sterically congested bis(imino)bipyridine complexes of zinc(II) and nickel(II)
Griffith, Gerry A.
Al-Khatib, Mohamed J.
Patel, Kalpana
Singh, Kuldip
Solan, Gregory A.
DALTON TRANSACTIONS, 2009, (01) : 185 - 196
[6] A COMPARATIVE XANES STUDY OF SOME COPPER(II) COMPLEXES IN SOLID-STATE AND SOLUTION FORM
SHRIVASTAVA, BD
MISHRA, A
JOSHI, SK
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 : 839 - 841
[7] Preparation and solid-state characterization of nickel(II) complexes with 1′-(diphenylphosphino)ferrocenecarboxylic acid
Pinkas, J
Bastl, Z
Slouf, M
Podlaha, J
Stepnicka, P
NEW JOURNAL OF CHEMISTRY, 2001, 25 (09) : 1215 - 1220
[8] SYNTHESIS, CHARACTERIZATION AND SOLID-STATE THERMAL-BEHAVIOR OF NICKEL(II) DIAMINE COMPLEXES
GHOSH, A
DE, G
CHAUDHURI, NR
TRANSITION METAL CHEMISTRY, 1986, 11 (03) : 81 - 86
[9] Divergent Solution and Solid-State Structures of Mono- and Dinuclear Nickel(II) Pyridone Complexes
Goralski, Sean T.
Manes, Taylor A.
Lumsden, Simone E. A.
Lynch, Vincent M.
Rose, Michael J.
ORGANOMETALLICS, 2020, 39 (07) : 1070 - 1079
[10] [COPPER(II)-ARYLTETRAAZANNULENE]IX COMPLEXES AS CONDUCTIVE MATERIALS - SOLID-STATE SYNTHESIS AND CHARACTERIZATION
LELJ, F
MORELLI, G
RICCIARDI, G
ROMANELLI, M
ROSA, A
OTTAVIANI, MF
POLYHEDRON, 1991, 10 (16) : 1911 - 1919

← 1 2 3 4 5 →