A concise synthesis of indene-based polycyclic compounds via FeCl3-catalyzed cascade cyclization

被引：11
|
作者：
Su, Xiang [1 ]
Wu, Panpan [2 ,3 ]
Liu, Wenfeng [2 ,3 ]
Chen, Chao [1 ,2 ,3 ]
机构：
[1] Tsinghua Univ, Minist Educ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
[2] Wuyi Univ, Sch Chem & Environm Engn, Jiangmen 529000, Peoples R China
[3] Int Healthcare Innovat Inst Jiangmen, Jiangmen 529000, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 07期
基金：
中国国家自然科学基金;
关键词：
PROPARGYLIC ALCOHOLS; ORGANIC-SYNTHESIS; DERIVATIVES; ALKYNES; CYCLOADDITION; COMPLEXES; POLYMERIZATION; ACTIVATION; ANNULATION; LIGANDS;
D O I：
10.1039/c8qo00004b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and straightforward protocol to complex indene-based polycyclic compounds via the cascade cyclization of propargylic alcohols and alkenes was developed. The catalyst FeCl3, as an Earth-abundant and environment friendly transition metal salt, is attractive. This reaction proceeded through unusual C-C bond cleavage.
引用
收藏
页码：1165 / 1169
页数：5
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