Heteronuclear dipolar coupling in spin-1 NQR pulsed spin locking

被引:1
|
作者
Malone, M. W. [1 ]
Sauer, K. L. [1 ]
机构
[1] George Mason Univ, Fairfax, VA 22030 USA
关键词
Nuclear quadrupole resonance; Spin-locking; Dipolar coupling; Broadening; CRYSTAL;
D O I
10.1016/j.jmr.2013.10.014
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
We investigate theoretically and experimentally the role of broadening due to heteronuclear dipolar coupling in spin-1 nuclear quadrupole resonance pulsed spin locking. We find the experimental conditions where heteronuclear dipolar coupling is refocused by a standard multipulse sequence. This experimental condition allows us to extend our previously reported ability to measure the homonuclear dipolar coupling of powder samples to include substances that have heteronuclear coupling. These results are useful for designing substance detection algorithms, and for performing sample characterization. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码:8 / 15
页数:8
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