Rhodium Catalysts Bearing Mixed Thioether-Phosphine Ligands for Carbonylation of Methanol

被引：4
|
作者：
Sakakibara, Ken [1 ]
Nozaki, Kyoko [1 ]
机构：
[1] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2009年 / 82卷 / 08期
基金：
日本学术振兴会;
关键词：
MOLECULAR-STRUCTURE; CRYSTAL; COMPLEXES; ACID;
D O I：
10.1246/bcsj.82.1009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two kinds of thioether-trialkylphosphine ligands and their Rh complexes were synthesized and applied to the carbonylation of methanol to acetic acid to reveal that one of the two complexes showed higher activity compared to Rh catalyst without any ligands.
引用
收藏
页码：1009 / 1011
页数：3
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