Chiral copper-catalyzed asymmetric monoarylation of vicinal diols with diaryliodonium salts

被引：10
|
作者：
Hamaguchi, Norihisa [1 ]
Kuriyama, Masami [1 ]
Onomura, Osamu [1 ]
机构：
[1] Nagasaki Univ, Grad Sch Biomed Sci, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan
来源：
TETRAHEDRON-ASYMMETRY | 2016年 / 27卷 / 4-5期
关键词：
POLYBROMINATED DIPHENYL ETHERS; DYNAMIC KINETIC RESOLUTION; METAL-FREE ARYLATION; C-H; ENANTIOSELECTIVE SYNTHESIS; DIARYL ETHERS; DESYMMETRIZATION; ACYLATION; ALCOHOLS; MONOPHENYLATION;
D O I：
10.1016/j.tetasy.2016.01.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The copper-catalyzed enantioselective monoarylation of meso-1,2-diols by the use of diaryliodonium triflates as aryl sources has been developed. The chiral copper(II) complex catalyzed the asymmetric desymmetrization effectively to afford optically active beta-aryloxy alcohols in moderate to high chemical yields and enantioselectivity. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：177 / 181
页数：5
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