Mn(III)-based oxidative tandem free-radical cyclizations of methylenecyclopropanes with substituted dicarbonyl compounds

被引：15

作者：

Fu, Wei-Jun

Huang, Xian

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Oganomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 04期

基金：

中国国家自然科学基金;

关键词：

radical cyclization; methylenecyclopropanes; manganese(III) acetate; substituted dicarbonyl compounds; dihydronaphthalene derivatives;

D O I：

10.1016/j.jorganchem.2006.10.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Manganese(III) acetate-mediated tandem radical cyclization reactions of methylenecyclopropanes with methyl substituted dicarbonyl compounds in acetic acid give dihydronaphthalene derivatives in moderate yields under mild conditions. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：740 / 745

页数：6

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