Stereospecific interconversion between cis and trans 2,3-epoxysulfides

被引：0
|
作者：
Hirai, A [1 ]
Tonooka, T [1 ]
Wakatsuki, K [1 ]
Tanino, K [1 ]
Miyashita, M [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 05期
关键词：
bromohydrins; epoxidation; isomerization; nucleophilic substitution; synthetic methods;
D O I：
10.1002/1521-3773(20020301)41:5<819::AID-ANIE819>3.0.CO;2-J
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A double inversion of configuration and episulfonium ion intermediates are at the heart of a method for the stereospecific interconversion between cis and trans 2,3-epoxysulfides (see scheme). This method can be used in the stereoselective synthesis of epoxides.
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页码：819 / +
页数：4
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