Hydrogen-bonding catalysis of sulfonium salts

被引：37

作者：

Kaneko, Shiho ^{[1
]}

Kumatabara, Yusuke ^{[1
]}

Shimizu, Shoichi ^{[2
]}

Maruoka, Keiji ^{[3
]}

Shirakawa, Seiji ^{[1
]}

机构：

[1] Nagasaki Univ, Grad Sch Fisheries & Environm Sci, Dept Environm Sci, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan

[2] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, Izumi Cho, Narashino, Chiba 2758575, Japan

[3] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 01期

关键词：

QUATERNARY PHOSPHONIUM SALTS; DIRECT REDUCTIVE AMINATION; PHASE-TRANSFER CATALYSTS; ANION-BINDING CATALYSIS; DIELS-ALDER REACTION; ENANTIOSELECTIVE SYNTHESIS; TETRAALKYLAMMONIUM SALTS; DANISHEFSKYS DIENE; CARBONYL-COMPOUNDS; ORGANOCATALYSIS;

D O I：

10.1039/c6cc08411g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although quaternary ammonium and phosphonium salts are known as important catalysts in phase-transfer catalysis, the catalytic ability of tertiary sulfonium salts has not yet been well demonstrated. Herein, we demonstrate the catalytic ability of trialkylsulfonium salts as hydrogenbonding catalysts on the basis of the characteristic properties of the acidic a hydrogen atoms on alkylsulfonium salts.

引用

页码：119 / 122

页数：4

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