Managing metolachlor and atrazine leaching losses using lignite fly ash

Application of low cost amendment for pesticide retention in soil is an important area of research in environmental sciences. The present study reports the potential of coal fly ash (Inderprastha and Badarpur), a waste from thermal power stations, for retaining soil applied metolachlor and atrazine within the application zone. Both the fly ashes were highly effective in reducing the leaching losses of metolachlor and atrazine and at 2% and 5% fly ash amendment levels the herbicides were retained in the top 15 cm profile of the column. However, fly ashes varied in their capacity in reducing the downward mobility of herbicides, as the Inderprastha fly ash was more effective than the Badarpur fly ash. Although fly ash contained heavy metals like Cr, Cu or Pb, but they were not detected in the leachate. Also, concentration of other metals like Zn, Mn and Fe in leachate decreased after fly ash amendment. Results of this study have implications in reducing the leaching losses of these herbicides in agricultural soils. (C) 2012 Elsevier Inc. All rights reserved.