Cross-dehydrogenative Coupling Reactions Between Formamidic C(sp2)-H and X-H (X = C, O, N) Bonds

被引：18
|
作者：
He, Zhe [1 ]
Wu, Dan [1 ]
Vessally, Esmail [2 ]
机构：
[1] Liaoning Univ, Sch Environm, Shenyang 110036, Peoples R China
[2] Payame Noor Univ, Dept Chem, Tehran, Iran
来源：
TOPICS IN CURRENT CHEMISTRY | 2020年 / 378卷 / 06期
关键词：
Cross-dehydrogenative couplings; Carbamoylation; Formamides; Carboxamides; Carbamates; Ureas; C-H bond; O-H bond; N-H bond; METAL-FREE; CATALYZED CARBAMOYLATION; UREA DERIVATIVES; ARYL FORMAMIDES; NANO-CATALYSTS; ACTIVATION; AMIDES; NANOCATALYSTS; NANOPARTICLES; PHENOLS;
D O I：
10.1007/s41061-020-00309-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the last decade, the scientific community has witnessed explosive growth in research on the direct carbamoylation of C-H and X-H (X = N, O) bonds with formamides via cross-dehydrogenative coupling reactions. This novel approach is an effective means of preparing a variety of carboxamide, carbamate as well as urea derivatives, which are prevalent in medicinal chemistry and natural product synthesis. This review elaborates the most important advances and developments in the field, with an emphasis on the reaction patterns and mechanisms.
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页数：30
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