Self-assembly of a chiral phosphinegold(I) building block into a two-dimensional netsheet based on a hydrogen bond between one Cl- anion and three hydroxy groups, co-ordination and aurophilicity interactions

The trigold(I) complex [{Au(mbpa)}(3)S]Cl 2 [mbpa = methyl 4,6-O-benzylidene-3-deoxy-3-(diphenylphosphino)-alpha-D-altropyranoside] has been obtained from the compound [Au(mpba)Cl] land L-cysteine. Complex 2 crystallizes in space group P6(6) with a = 15.165(2), c = 18.897(3) Angstrom and Z = 2, R = 0.030, R' = 0.050. The crystal structure shows that the Au3S core is a perfect trigonal pyramid with angles Au-S-Au and P-Au-S of 88.7 and 179.6 degrees, respectively, and that the chiral building blocks [{Au(mpba)}(3)S](+) assemble through triple hydrogen bonding between one hydrogen-bond acceptor, Cl-, and three hydrogen-bond donors [Cl ... O(2) 3.017(10) Angstrom], and form infinite two-dimensional netsheets. The netsheets align in the same direction. A relativistic interaction of the d(10) closed shell of gold(I) was revealed by NMR studies. Complex 2 displays a strong bright white emission at 495 nm when excited at 303 nm at room temperature, where the lowest-energy transition is of metal-to-ligand charge-transfer (Au-->S) type.