Crosslinking free-radical living copolymerization of styrene with divinyl sulfide in the presence of N,N′-bis(vinyloxyethyl)thiuram disullfide

被引：0
|
作者：
Amosova, SV [1 ]
Biryukova, EI [1 ]
Brodskaya, EI [1 ]
Zhivet'eva, SA [1 ]
Gromkova, RA [1 ]
机构：
[1] Russian Acad Sci, Favorskii Inst Chem, Irkutsk 664033, Russia
来源：
POLYMER SCIENCE SERIES A | 2004年 / 46卷 / 03期
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D O I：
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Network copolymers of styrene with divinyl sulfide were synthesized in the presence of an agent of free-radical living polymerization, N,N'-bis(vinyloxyethyl)thiuram disulfide. A quick IR spectroscopy test for determining copolymer composition was developed. The reactivity of monomers, the composition of copolymers, and the kinetics of polymerization were studied. The manifestation of the gel effect at higher conversions suggests that the copolymerization proceeds by the living chain mechanism.
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页码：289 / 294
页数：6
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