Direct incorporation of carbon dioxide in poly(glycidyl methacrylate) and its application to the synthesis of hydrogel

被引：3
|
作者：
Park, DW [1 ]
Kim, KH [1 ]
Park, SY [1 ]
Sung, CK [1 ]
Park, SW [1 ]
机构：
[1] Pusan Natl Univ, RIIT, Dept Chem Engn, Pusan 609735, South Korea
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2002年 / 75卷 / 02期
关键词：
hydrogel; carbon dioxide; poly(hydroxyurethane); quaternary ammonium salts;
D O I：
10.1023/A:1015271501516
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This study is related to an integrated process for the application of CO2 to poly(hydroxy urethane) and hydrogel via poly(1,3-dioxolane-2-oxo-4-yl)methyl methacrylate [poly (DOMA)]. Quaternary ammonium salts showed good catalytic activity in the synthesis of poly(DOMA) by the direct incorporation of CO2 into poly(glycidyl methacrylate) [poly(GMA)]. Poly[3-(N-butylcarbamoyloxy)-2-hydroxypropyl methacrylate] [poly(CHPMA)] was successfully synthesized from poly(DOMA) and n-butylamine. Hydrogels were also prepared from the poly(CHPMA), using several diisocyanates as crosslinkers, and their swelling degrees were studied by measuring water content in the hydrogels.
引用
收藏
页码：375 / 383
页数：9
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