Encapsulation of small organic molecules by a self-assembled molecular capsule through charged hydrogen bonding interaction

被引：51
|
作者：
Lee, SB [1 ]
Hong, JI [1 ]
机构：
[1] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151742,SOUTH KOREA
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 47期
关键词：
D O I：
10.1016/0040-4039(96)01950-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Self-assembled heterodimeric molecular capsule based on the charged hydrogen bonding interaction between two different CTV monomers (1 and 2) was developed. The formation of the molecular capsule was confirmed by inclusion phenomena of complementary neutral guests in DMSO-d(6). The encapsulated TMS was released by prolonged heating or pH adjustment. Molecular modeling and intermolecular NOEs suggested the three-dimensional structure of the termolecular inclusion complex. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：8501 / 8504
页数：4
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