Design of Magnetic Polyoxometalates for Molecular Spintronics and as Spin Qubits

被引:25
|
作者
Baldovi, J. J. [1 ]
Cardona-Serra, S. [1 ]
Gaita-Arino, A. [1 ]
Coronado, E. [1 ]
机构
[1] Univ Valencia, Inst Ciencia Mol ICMol, Paterna, Spain
关键词
MIXED-VALENCE POLYOXOMETALATE; INELASTIC NEUTRON-SCATTERING; SINGLE-ION MAGNETS; AB-INITIO CALCULATIONS; ELECTRIC-FIELD CONTROL; LANTHANIDE COMPLEXES; QUANTUM COHERENCE; KEGGIN STRUCTURE; EXCHANGE INTERACTIONS; RATIONAL DESIGN;
D O I
10.1016/bs.adioch.2016.12.003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the past decades, POMs have been used as minimal models in Molecular Magnetism, since they are a convenient playing ground to study fundamental phenomena such as anisotropic magnetic exchange and electron transfer. Now they have jumped to the stage of the rational design of single-ion magnets and are being considered as test subjects for simple experiments in Single-Molecule Spintronics and Molecular Quantum Computing. This chapter contains an overview of recent results that demonstrate the potential of POMs in these emerging fields.
引用
收藏
页码:213 / 249
页数:37
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