Microwave-assisted synthesis of urea-containing zirconium metal-organic frameworks for heterogeneous catalysis of Henry reactions

被引：26

作者：

Zhang, He ^{[1
,2
]}

Gao, Xue-Wang ^{[3
]}

Wang, Li ^{[1
,2
]}

Zhao, Xinsheng ^{[1
,2
]}

Li, Qiu-Yan ^{[1
,2
]}

Wang, Xiao-Jun ^{[1
,2
,3
,4
,5
]}

机构：

[1] Jiangsu Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Sch Chem & Mat Sci, Xuzhou 221116, Jiangsu, Peoples R China

[2] Jiangsu Normal Univ, Sch Phys & Elect Engn, Xuzhou 221116, Jiangsu, Peoples R China

[3] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[4] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

[5] Shantou Univ, Key Lab Preparat & Applicat Ordered Struct Mat Gu, Shantou 515063, Guangdong, Peoples R China

来源：

CRYSTENGCOMM | 2019年 / 21卷 / 09期

基金：

中国国家自然科学基金;

关键词：

CLICK CHEMISTRY; BOND DONORS; MOFS; ORGANOCATALYSIS; DESIGN; CONSTRUCTION; INDOLES;

D O I：

10.1039/c8ce02153h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report the facile preparation of a urea-containing UiO-68 isoreticular zirconium metal-organic framework (MOF) with mixed dicarboxylate struts by utilizing a microwave-assisted heating method. It can work as an efficient hydrogen-bond-donating heterogeneous catalyst for Henry reactions of benzaldehydes and nitroalkanes. This mixed strut MOF exhibits improved catalytic activity compared to the pure urea-functionalized linker based analogue.

引用

页码：1358 / 1362

页数：5

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