The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main- Chain Porphyrin Oligomers

被引：3

作者：

Konev, Alexander S. ^{[1
]}

Lukyanov, Daniil A. ^{[1
]}

Vlasov, Petr S. ^{[1
]}

Levin, Oleg V. ^{[1
]}

Virtsev, Alexander A. ^{[1
]}

Kislyakov, Ivan M. ^{[2
]}

Khlebnikov, Alexander F. ^{[1
]}

机构：

[1] St Petersburg State Univ, Dept Chem, St Petersburg 198504, Russia

[2] Univ ITMO, St Petersburg 197101, Russia

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2014年 / 215卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

conducting polymers; electrochemistry; optical power limiting; polymerization; porphyrins; ONE-POT SYNTHESIS; CLICK POLYMERIZATION; MESOSUBSTITUTED PORPHYRINS; STEREOSELECTIVE-SYNTHESIS; CONTAINING POLYMERS; METAL DERIVATIVES; BUILDING-BLOCKS; POLYCYCLOADDITION; FLUORESCENCE; DENDRIMERS;

D O I：

10.1002/macp.201300679

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polycycloaddition of azomethine ylides to dipolarophiles is described for the first time. Use of (cis,cis)-bis-aziridines as a source of azomethine ylides allows selective polyaddition to be realized, which leads to oligomers exclusively with trans-substituted pyrrolidine rings and modest molecular weights (ca. 5-10 kDa). The fluorescent, electrochemical, electrochromic, and non-linear optical properties of the main-chain free-base porphyrin oligomer, synthesized by the developed procedure, are studied. An enhancement of the optical power limiting effect in a porphyrin oligomer solution is registered against that of the monomer. <boxed-text content-type="graphic" position="anchor"> <graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="urn:x-wiley:10221352:media:macp201300679:macp201300679-abs-0001">image</graphic

引用

页码：516 / 529

页数：14

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